1.14.20.12: 3-[(E)-2-isocyanoethenyl]-1H-indole synthase

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Reaction

Synonyms

isnB

ECTree

     1 Oxidoreductases

         1.14 Acting on paired donors, with incorporation or reduction of molecular oxygen

             1.14.20 With 2-oxoglutarate as one donor, and the other dehydrogenated

                1.14.20.12 3-[(E)-2-isocyanoethenyl]-1H-indole synthase

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Systematic Name

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Systematic Name on EC 1.14.20.12 - 3-[(E)-2-isocyanoethenyl]-1H-indole synthase

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SYSTEMATIC NAME

IUBMB Comments

(2S)-3-(1H-indol-3-yl)-2-isocyanopropanoate,2-oxoglutarate:oxygen oxidoreductase (decarboxylating, 3-[(E)-2-isocyanoethenyl]-1H-indole-forming)

The enzyme has been characterized from an unidentified soil bacterium. It catalyses an Fe2+, 2-oxoglutarate-dependent monooxygenation at C-3, which is followed by decarboxylation and dehydration, resulting in the generation of a trans C-C double bond. cf. EC 1.14.20.11, 3-[(Z)-2-isocyanoethenyl]-1H-indole synthase.