1.14.14.135: glyceollin synthase

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For detailed information about glyceollin synthase, go to the full flat file.

+ 2 H2O

dimethylallyl-3,6a,9-trihydroxypterocarpan cyclase, EC 1.14.13.85

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Results	in table
2	Activating Compound
1	CAS Registry Number
3	Cofactor
13	Inhibitors
2	KM Value [mM]
2	Localization
1	Natural Substrates/ Products (Substrates)
1	Organism
3	Pathway
1	pH Optimum
1	pH Range
4	Reaction
3	Reaction Type
1	Reference
1	Source Tissue
1	Specific Activity [micromol/min/mg]
4	Substrates and Products (Substrate)
2	Synonyms
1	Systematic Name
1	Temperature Optimum [°C]

Substrates Products on EC 1.14.14.135 - glyceollin synthase

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2-(or 4-)dimethylallyl-(6aS,11aS)-3,6a,9-trihydroxypterocarpan + [reduced NADPH-hemoprotein reductase] + O2

glyceollin + [oxidized NADPH-hemoprotein reductase] + H2O

enzyme catalyzes an NADPH-dependent and oxygen-dependent cyclization of a mixture of 2- and 4-dimethylallylglycinols to the glyceollin isomers I-III

glyceollin isomers I-III, glyceollin isomer I is formed from 4-dimethylallylglycinol and glyceollin isomers II and III from 2-dimethylallylglycinol

glyceollin II + NADPH + H+ + H2O

2-dimethylallyl-(6aS,11aS)-3,6a,9-trihydroxypterocarpan + NADP+ + O2

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