1.14.14.135: glyceollin synthase
This is an abbreviated version!
For detailed information about glyceollin synthase, go to the full flat file.
Reaction
Synonyms
dimethylallyl-3,6a,9-trihydroxypterocarpan cyclase, EC 1.14.13.85
ECTree
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Reaction
Reaction on EC 1.14.14.135 - glyceollin synthase
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2-dimethylallyl-(6aS,11aS)-3,6a,9-trihydroxypterocarpan + [reduced NADPH-hemoprotein reductase] + O2 = glyceollin II + [oxidized NADPH-hemoprotein reductase] + 2 H2O
2-dimethylallyl-(6aS,11aS)-3,6a,9-trihydroxypterocarpan + [reduced NADPH-hemoprotein reductase] + O2 = glyceollin III + [oxidized NADPH-hemoprotein reductase] + 2 H2O
(2)
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4-dimethylallyl-(6aS,11aS)-3,6a,9-trihydroxypterocarpan + [reduced NADPH-hemoprotein reductase] + O2 = glyceollin I + [oxidized NADPH-hemoprotein reductase] + 2 H2O
(3)
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2-dimethylallyl-(6aS,11aS)-3,6a,9-trihydroxypterocarpan + [reduced NADPH-hemoprotein reductase] + O2 = glyceollin II + [oxidized NADPH-hemoprotein reductase] + 2 H2O
a heme-thiolate protein, P-450, glyceollins II and III are formed from 2-dimethylallyl-(6aS,11aS)-3,6a,9-trihydroxypterocarpan whereas glyceollin I is formed from the 4-isomer
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