EC Explorer
[browse EC tree] - [search]
EC 1.14.11.43 Details
show Brenda entryEC number
1.14.11.43
Accepted name
(S)-dichlorprop dioxygenase (2-oxoglutarate)
Reaction
(1) (S)-2-(4-chloro-2-methylphenoxy)propanoate + 2-oxoglutarate + O2 = 4-chloro-2-methylphenol + pyruvate + succinate + CO2;;
(2) (S)-(2,4-dichlorophenoxy)propanoate + 2-oxoglutarate + O2 = 2,4-dichlorophenol + pyruvate + succinate + CO2
Other name(s)
SdpA,
α-ketoglutarate-dependent (S)-dichlorprop dioxygenase,
(S)-phenoxypropionate/α-ketoglutarate-dioxygenase,
2-oxoglutarate-dependent (S)-dichlorprop dioxygenase,
(S)-mecoprop dioxygenase,
2-oxoglutarate-dependent (S)-mecoprop dioxygenase
Systematic name
(S)-2-(4-chloro-2-methylphenoxy)propanoate,2-oxoglutarate:oxygen oxidoreductase (pyruvate-forming)
Comment
Fe2+-dependent enzyme. The enzymes from the Gram-negative bacteria Delftia acidovorans MC1 and Sphingomonas herbicidovorans MH are involved in the degradation of the (S)-enantiomer of the phenoxyalkanoic acid herbicides mecoprop and dichlorprop [1,2].
History
created 2013
back to topEC Tree
1 Oxidoreductases
1.1 Acting on the CH-OH group of donors
1.14.11.5 created 1972, deleted 1976
