2.5.1.111: 4-hydroxyphenylpyruvate 3-dimethylallyltransferase

This is an abbreviated version!
For detailed information about 4-hydroxyphenylpyruvate 3-dimethylallyltransferase, go to the full flat file.

Reaction

Synonyms

4HPP dimethylallyltransferase, apT, aromatic prenyltransferase, CloQ, FamD1, isoprenyl transferase, NovQ

ECTree

     2 Transferases

         2.5 Transferring alkyl or aryl groups, other than methyl groups

             2.5.1 Transferring alkyl or aryl groups, other than methyl groups (only sub-subclass identified to date)

                2.5.1.111 4-hydroxyphenylpyruvate 3-dimethylallyltransferase

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Results	in table
5	AA Sequence
2	Application
8	Cloned(Commentary)
4	Crystallization (Commentary)
1	Expression
4	General Information
3	Inhibitors
13	kcat/KM [mM/s]
17	KM Value [mM]
8	Metals/Ions
3	Molecular Weight [Da]
10	Natural Substrates/ Products (Substrates)
18	Organism
3	Pathway
4	pH Optimum
23	Protein Variants
7	Purification (Commentary)
1	Reaction
16	Reference
51	Substrates and Products (Substrate)
8	Subunits
22	Synonyms
1	Systematic Name
4	Temperature Optimum [°C]
15	Turnover Number [1/s]

KM Value

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KM Value on EC 2.5.1.111 - 4-hydroxyphenylpyruvate 3-dimethylallyltransferase

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KM VALUE [mM]

SUBSTRATE

ORGANISM

UNIPROT

COMMENTARY

LITERATURE

IMAGE

0.0151 - 0.025

4-hydroxyphenylpyruvate

4 entries

0.025 - 0.035

dimethylallyl diphosphate

3 entries

0.1044 - 0.5202

menadione hydroquinol

10 entries

0.0151

4-hydroxyphenylpyruvate

Streptomyces niveus

Q9L9F1

pH 7.5, 30°C

722465

0.016

4-hydroxyphenylpyruvate

Streptomyces roseochromogenus subsp. oscitans

Q8GHB2

pH 7.5, 30°C, wild-type enzyme

722973

0.025

4-hydroxyphenylpyruvate

Streptomyces roseochromogenus subsp. oscitans

Q8GHB2

pH 7.5, 30°C

723616

0.025

4-hydroxyphenylpyruvate

Streptomyces roseochromogenus subsp. oscitans

Q8GHB2

pH 7.5, 30°C, C215 mutant enzyme

722973

0.025

dimethylallyl diphosphate

Streptomyces roseochromogenus subsp. oscitans

Q8GHB2

pH 7.5, 30°C, wild-type

722973

0.0333

dimethylallyl diphosphate

Streptomyces niveus

Q9L9F1

pH 7.5, 30°C

722465

0.035

dimethylallyl diphosphate

Streptomyces roseochromogenus subsp. oscitans

Q8GHB2

pH 7.5, 30°C

723616

0.1044

menadione hydroquinol

Streptomyces niveus

Q9L9F1

mutant enzyme E281R, at pH 8.0 and 32°C

758689

0.1537

menadione hydroquinol

Streptomyces niveus

Q9L9F1

mutant enzyme E281Q, at pH 8.0 and 32°C

758689

0.1737

menadione hydroquinol

Streptomyces niveus

Q9L9F1

wild type enzyme, at pH 8.0 and 32°C

758689

0.2106

menadione hydroquinol

Streptomyces niveus

Q9L9F1

mutant enzyme E281M, at pH 8.0 and 32°C

758689

0.2181

menadione hydroquinol

Streptomyces niveus

Q9L9F1

mutant enzyme E281K, at pH 8.0 and 32°C

758689

0.2933

menadione hydroquinol

Streptomyces niveus

Q9L9F1

mutant enzyme E281V, at pH 8.0 and 32°C

758689

0.3623

menadione hydroquinol

Streptomyces niveus

Q9L9F1

mutant enzyme E281A, at pH 8.0 and 32°C

758689

0.4097

menadione hydroquinol

Streptomyces niveus

Q9L9F1

mutant enzyme E281S, at pH 8.0 and 32°C

758689

0.4799

menadione hydroquinol

Streptomyces niveus

Q9L9F1

mutant enzyme E281T, at pH 8.0 and 32°C

758689

0.5202

menadione hydroquinol

Streptomyces niveus

Q9L9F1

mutant enzyme E281D, at pH 8.0 and 32°C

758689