EC Number |
Substrates |
Organism |
Products |
Reversibility |
---|
2.5.1.69 | 2 dimethylallyl diphosphate |
reaction of EC 2.5.1.67, chrysanthemyl diphosphate synthase, a cyclopropanation |
Artemisia spiciformis |
diphosphate + chrysanthemyl diphosphate |
an irregular monoterpene product |
? |
2.5.1.69 | 2 dimethylallyl diphosphate |
reaction of EC 2.5.1.67, chrysanthemyl diphosphate synthase is an inefficient promiscuous enzyme, which synthesizes the irregular monoterpenes chrysanthemyl diphosphate (CPP), lavandulyl diphosphate (LPP), and trace quantities of maconelliyl diphosphate (MPP) from two molecules of DMAPP, and couples IPP to DMAPP to give GPP |
Artemisia spiciformis |
diphosphate + chrysanthemyl diphosphate |
- |
? |
2.5.1.69 | 2 dimethylallyl diphosphate |
- |
Lavandula x intermedia |
diphosphate + lavandulyl diphosphate |
- |
? |
2.5.1.69 | 2 dimethylallyl diphosphate |
- |
Lavandula lanata |
diphosphate + lavandulyl diphosphate |
- |
? |
2.5.1.69 | 2 dimethylallyl diphosphate |
a branching reaction |
Artemisia spiciformis |
diphosphate + lavandulyl diphosphate |
- |
? |
2.5.1.69 | 2 dimethylallyl diphosphate |
enzyme specifically catalyzes the head-to-middle condensation of two dimethylallyl diphosphate units to lavandulyl diphosphate |
Lavandula x intermedia |
diphosphate + lavandulyl diphosphate |
- |
? |
2.5.1.69 | 2 dimethylallyl diphosphate |
chrysanthemyl diphosphate synthase is an inefficient promiscuous enzyme, which synthesizes the irregular monoterpenes chrysanthemyl diphosphate (CPP), lavandulyl diphosphate (LPP), and trace quantities of maconelliyl diphosphate (MPP) from two molecules of DMAPP, and couples IPP to DMAPP to give GPP |
Artemisia spiciformis |
diphosphate + lavandulyl diphosphate |
- |
? |
2.5.1.69 | 2 dimethylallyl diphosphate |
the product lavandulyl diphosphate is a precursor to the fragrance lavandulol |
Lavandula lanata |
diphosphate + lavandulyl diphosphate |
- |
? |
2.5.1.69 | 2 dimethylallyl diphosphate |
- |
Artemisia tridentata |
(R)-lavandulol + (R)-maconelliol + diphosphate |
in presence of alkaline phosphatase, chimera c98f produces a 6:5 mixture of (R)-lavandulol and (R)-maconelliol and a small amount of planococcyl alcohol |
? |
2.5.1.69 | dimethylallyl diphosphate + isopentenyl diphosphate |
reaction of EC 2.5.1.1, chrysanthemyl diphosphate synthase is an inefficient promiscuous enzyme, which synthesizes the irregular monoterpenes chrysanthemyl diphosphate (CPP), lavandulyl diphosphate (LPP), and trace quantities of maconelliyl diphosphate (MPP) from two molecules of DMAPP, and couples IPP to DMAPP to give GPP |
Artemisia spiciformis |
diphosphate + geranyl diphosphate |
- |
? |