EC Number |
Substrates |
Organism |
Products |
Reversibility |
---|
2.5.1.67 | 2 dimethylallyl diphosphate |
- |
Tanacetum cinerariifolium |
diphosphate + chrysanthemyl diphosphate |
- |
? |
2.5.1.67 | 2 dimethylallyl diphosphate |
- |
Artemisia spiciformis |
diphosphate + chrysanthemyl diphosphate |
- |
? |
2.5.1.67 | 2 dimethylallyl diphosphate |
- |
Tanacetum cinerariifolium |
diphosphate + chrysanthemyl diphosphate |
product analysis, chrysanthemyl diphosphate is an irregular monoterpene with a non-head-to-tail or irregular c1'-2-3 linkage between isoprenoid units |
? |
2.5.1.67 | 2 dimethylallyl diphosphate |
multistep cyclization cascade, biosynthesic pathway, and family tree of terpenomic diversity, overview |
Artemisia spiciformis |
diphosphate + chrysanthemyl diphosphate |
- |
? |
2.5.1.67 | 2 dimethylallyl diphosphate |
a cyclopropanation |
Artemisia spiciformis |
diphosphate + chrysanthemyl diphosphate |
an irregular monoterpene product |
? |
2.5.1.67 | 2 dimethylallyl diphosphate |
the enzyme catalyzes c1'-2-3 cyclopropanation reactions of two molecules of dimethylallyl diphosphate to yield chrysanthemyl diphosphate |
Tanacetum cinerariifolium |
diphosphate + chrysanthemyl diphosphate |
- |
? |
2.5.1.67 | 2 dimethylallyl diphosphate |
chrysanthemyl diphosphate synthase is an inefficient promiscuous enzyme, which synthesizes the irregular monoterpenes chrysanthemyl diphosphate (CPP), lavandulyl diphosphate (LPP), and trace quantities of maconelliyl diphosphate (MPP) from two molecules of DMAPP, and couples IPP to DMAPP to give GPP |
Artemisia spiciformis |
diphosphate + chrysanthemyl diphosphate |
- |
? |
2.5.1.67 | 2 dimethylallyl diphosphate |
reaction of EC 2.5.1.69, lavandulyl diphosphate synthase, a branching reaction |
Artemisia spiciformis |
diphosphate + lavandulyl diphosphate |
- |
? |
2.5.1.67 | 2 dimethylallyl diphosphate |
reaction of EC 2.5.1.69, chrysanthemyl diphosphate synthase is an inefficient promiscuous enzyme, which synthesizes the irregular monoterpenes chrysanthemyl diphosphate (CPP), lavandulyl diphosphate (LPP), and trace quantities of maconelliyl diphosphate (MPP) from two molecules of DMAPP, and couples IPP to DMAPP to give GPP |
Artemisia spiciformis |
diphosphate + lavandulyl diphosphate |
- |
? |
2.5.1.67 | 6 dimethylallyl diphosphate |
- |
Artemisia spiciformis |
(R)-lavandulyl diphosphate + (R)-maconelliyl diphosphate + (1R,3R)-chyrsanthemyl diphosphate + 3 diphosphate |
non-head-to-tail alcohols after incubation of dimethylallyl diphosphate with CPP synthase followed by hydrolysis with alkaline phosphatase |
? |