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Information on EC 2.5.1.67 - chrysanthemyl diphosphate synthase

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IUBMB Comments
Requires a divalent metal ion for activity, with Mg2+ being better than Mn2+ . Chrysanthemyl diphosphate is a monoterpene with a non-head-to-tail linkage. It is unlike most monoterpenoids, which are derived from geranyl diphosphate and have isoprene units that are linked head-to-tail. The mechanism of its formation is similar to that of the early steps of {terp/squalphyto::squalene and phytoene biosynthesis}. Chrysanthemyl diphosphate is the precursor of chrysanthemic acid, the acid half of the pyrethroid insecticides found in chrysanthemums.
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Word Map
The enzyme appears in viruses and cellular organisms
Synonyms
cppase, chrysanthemyl diphosphate synthase, fds-5, chrysanthemol synthase, more
REACTION
REACTION DIAGRAM
COMMENTARY hide
ORGANISM
UNIPROT
LITERATURE
2 dimethylallyl diphosphate = diphosphate + chrysanthemyl diphosphate
show the reaction diagram
PATHWAY SOURCE
PATHWAYS
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