1.1.1.312: 2-hydroxy-4-carboxymuconate semialdehyde hemiacetal dehydrogenase
This is an abbreviated version!
For detailed information about 2-hydroxy-4-carboxymuconate semialdehyde hemiacetal dehydrogenase, go to the full flat file.
Word Map on EC 1.1.1.312
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1.1.1.312
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protocatechuate
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2-pyrone-4,6-dicarboxylate
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4,5-dioxygenase
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lignin
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sphingomonas
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ligab
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paucimobilis
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ochraceae
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vanillate
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4,5-cleavage
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hydratase
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syringate
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ecori
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dehydrogenases
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testosteroni
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putida
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nad+
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biotechnology
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4-oxalomesaconate
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comamonas
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oxaloacetate
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industry
- 1.1.1.312
- protocatechuate
- 2-pyrone-4,6-dicarboxylate
-
4,5-dioxygenase
- lignin
-
sphingomonas
- ligab
- paucimobilis
- ochraceae
- vanillate
-
4,5-cleavage
-
hydratase
- syringate
- ecori
- dehydrogenases
-
testosteroni
- putida
- nad+
- biotechnology
- 4-oxalomesaconate
-
comamonas
- oxaloacetate
- industry
Reaction
Synonyms
2-hydroxy-4-carboxymuconate 6-semialdehyde dehydrogenase, 2-hydroxy-4-carboxymuconate-6-semialdehyde dehydrogenase, 4-carboxy-2-hydroxy-cis,cis-muconate-6-semialdehyde:NADP+ oxidoreductase, 4-carboxy-2-hydroxymuconate-6-semialdehyde dehydrogenase, alpha-hydroxy-gamma-carboxymuconic epsilon-semialdehyde dehydrogenase, CHMS dehydrogenase, CHMS hydrolase, dehydrogenase, 2-hydroxy-4-carboxymuconate 6-semialdehyde, EC 1.2.1.45, PmdC
ECTree
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Systematic Name
Systematic Name on EC 1.1.1.312 - 2-hydroxy-4-carboxymuconate semialdehyde hemiacetal dehydrogenase
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4-carboxy-2-hydroxymuconate semialdehyde hemiacetal:NADP+ 2-oxidoreductase
The enzyme does not act on unsubstituted aliphatic or aromatic aldehydes or glucose; NAD+ can replace NADP+, but with lower affinity. The enzyme was initially believed to act on 4-carboxy-2-hydroxy-cis,cis-muconate 6-semialdehyde and produce 4-carboxy-2-hydroxy-cis,cis-muconate [1]. However, later studies showed that the substrate is the hemiacetal form [3], and the product is 2-oxo-2H-pyran-4,6-dicarboxylate [2,4].