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Information on EC 1.14.19.50 - noroxomaritidine synthase

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EC Tree
IUBMB Comments
A P-450 (heme-thiolate) enzyme. The enzyme, characterized from Narcissus pseudonarcissus (daffodil), forms the two enantiomers of the Amaryllidacea alkaloid noroxomaritidine by catalysing intramolecular oxidative para-para' phenol coupling. The oxidation involves molecular oxygen without its incorporation into the product.
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The enzyme appears in viruses and cellular organisms
Synonyms
cyp96t1, noroxomaritidine synthase, more
REACTION
REACTION DIAGRAM
COMMENTARY hide
ORGANISM
UNIPROT
LITERATURE
4'-O-methylnorbelladine + [reduced NADPH-hemoprotein reductase] + O2 = (4aR,10bS)-noroxomaritidine + [oxidized NADPH-hemoprotein reductase] + 2 H2O
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(1)
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4'-O-methylnorbelladine + [reduced NADPH-hemoprotein reductase] + O2 = (4aS,10bR)-noroxomaritidine + [oxidized NADPH-hemoprotein reductase] + 2 H2O
show the reaction diagram
(2)
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