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Information on EC 1.13.11.1 - catechol 1,2-dioxygenase
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1.13.11.1 catechol 1,2-dioxygenaseIUBMB Comments
Requires Fe3+. Involved in the metabolism of nitro-aromatic compounds by a strain of Pseudomonas putida.
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Word Map
- 1.13.11.1
- phenol
- benzoate
- protocatechuate
-
ortho
-
intradiol
-
3,4-dioxygenase
- muconate
-
cis,cis-muconic
- chlorocatechols
-
ortho-cleavage
- 4-chlorocatechol
-
cycloisomerase
-
ironiii
- 3-methylcatechol
- opacus
-
beta-ketoadipate
-
phenol-degrading
- gentisate
- 3-chlorobenzoate
-
2-hydroxymuconic
-
voxel-based
- radioresistens
-
3,5-di-tert-butylcatecholate
-
cis-muconate
-
meta-cleavage
-
clavien-dindo
- chlorobenzene
-
precuneus
- environmental protection
- degradation
- biotechnology
- synthesis
The expected taxonomic range for this enzyme is: Bacteria, Eukaryota, Archaea
Synonyms
catechol 1,2-dioxygenase, catechol dioxygenase, cat12, pyrocatechase, chlorocatechol 1,2-dioxygenase, cd ii, catechol 1,2-oxygenase, catechol 1,2 dioxygenase, 1,2-ctd, c1,2o, 
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SYNONYM 
ORGANISM
UNIPROT
COMMENTARY 
LITERATURE
(chloro-)catechol 1,2-dioxygenase
1,2 CTD
1,2-CTD
1,2-pyrocatechase
-
-
-
-
3-chlorocatechol 1,2-dioxygenase
C1,2-DO
C1,2O
C12
C12DO
C12O
cat12
CatA
catechase
-
-
-
-
catechol 1,2 dioxygenase
catechol 1,2-dioxygenase
catechol 1,2-dioxygenase type I
catechol 1,2-dioxygenase type II
catechol 1,2-oxygenase
-
-
-
-
catechol dioxygenase
-
-
-
-
catechol oxygenase
catechol-oxygen 1,2-oxidoreductase
-
-
-
-
catechol:oxygen 1,2-oxidoreductase
CD I
-
-
-
-
CD II
-
-
-
-
CD-I
-
-
-
-
CD-II
-
-
-
-
CD-III-1
-
-
-
-
CD-III-2
-
-
-
-
CDI1
-
-
-
-
CDI2
-
-
-
-
chlorocatechol 1,2-dioxygenase
clCA
IsoB
putative catechol 2,3-dioxygenase
involved in benzene metabolism
pyrocatechase
pyrocatechol 1,2-dioxygenase
-
-
-
-
catechol oxygenase
-
-
-
-
pyrocatechase
-
-
-
-
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REACTION
REACTION DIAGRAM
COMMENTARY
ORGANISM
UNIPROT
LITERATURE
catechol + O2 = cis,cis-muconate
-
-
-
-
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REACTION TYPE
ORGANISM
UNIPROT
COMMENTARY
LITERATURE
oxidation
redox reaction
reduction
-
-
-
-
oxidation
-
-
-
-
redox reaction
-
-
-
-
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PATHWAY SOURCE
PATHWAYS
KEGG
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SYSTEMATIC NAME
IUBMB Comments
catechol:oxygen 1,2-oxidoreductase
Requires Fe3+. Involved in the metabolism of nitro-aromatic compounds by a strain of Pseudomonas putida.
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CAS REGISTRY NUMBER
COMMENTARY
9027-16-1
-
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SUBSTRATE
PRODUCT
REACTION DIAGRAM
ORGANISM
UNIPROT
COMMENTARY
(Substrate)
(Substrate)
LITERATURE
(Substrate)
(Substrate)
COMMENTARY
(Product)
(Product)
LITERATURE
(Product)
(Product)
Reversibility
r=reversible
ir=irreversible
?=not specified
r=reversible
ir=irreversible
?=not specified
3-methylthiocatechol + O2
2-methylthio-cis,cis-muconate
-
very poor substrate
-
-
?
4-ethylcatechol + O2
4-ethyl-cis-cis-muconate
-
42% of activity with catechol
-
-
?
4-fluorocatechol + O2
4-fluoro-cis,cis-muconate
-
65% of activity with catechol
-
-
?
4-iso-propylcatechol + O2
4-isopropyl-cis,cis-muconate
-
23% of activity with catechol
-
-
?
4-methylcatechol + O2
3-methyl-cis,cis-hexadienedioate
-
-
-
?
4-n-propylcatechol + O2
4-n-propyl-cis,cis-muconate
-
17% of activity with catechol
-
-
?
catechol + O2
cis-cis muconate
assay at pH 8.0, 30°C
-
-
?
3,4-dimethylcatechol + O2
3,4-dimethyl-cis,cis-muconate
-
21% of activity with catechol
-
-
?
3,4-dimethylcatechol + O2
3,4-dimethyl-cis,cis-muconate
-
21% of activity with catechol
-
-
?
3,5-dichlorocatechol + O2
(2E,4E)-2,4-dichlorohexa-2,4-dienedioate
-
reaction catalyzed by catechol 1,2-dioxygenase type II
-
-
?
3,5-dichlorocatechol + O2
(2E,4E)-2,4-dichlorohexa-2,4-dienedioate
-
reaction catalyzed by catechol 1,2-dioxygenase type II
-
-
?
3,5-dichlorocatechol + O2
?
99.35% compared to the activity with catechol
-
-
?
3,5-dichlorocatechol + O2
?
Sphingobium scionense DSM 19371
99.35% compared to the activity with catechol
-
-
?
3,5-dimethylcatechol + O2
3,5-dimethyl-cis,cis-muconate
-
36% of activity with catechol
-
-
?
3,5-dimethylcatechol + O2
3,5-dimethyl-cis,cis-muconate
-
36% of activity with catechol
-
-
?
3-chloro-5-methylcatechol + O2
2-chloro-4-methylhexa-2,4-dienedioate
-
reaction catalyzed by catechol 1,2-dioxygenase type II
-
-
?
3-chloro-5-methylcatechol + O2
2-chloro-4-methylhexa-2,4-dienedioate
-
reaction catalyzed by catechol 1,2-dioxygenase type II
-
-
?
3-chlorocatechol + O2
2-chloro-cis,cis-muconate
CatA1: 4.4% of the activity with catechol
-
-
?
3-chlorocatechol + O2
2-chloro-cis,cis-muconate
CatA1: 4.4% of the activity with catechol
-
-
?
3-chlorocatechol + O2
2-chloro-cis,cis-muconate
-
pyrocatechase II, in 3-chlorobenzoate-grown cells
-
-
?
3-chlorocatechol + O2
2-chloro-cis,cis-muconate
Pseudomonas sp. B 13
-
pyrocatechase II, in 3-chlorobenzoate-grown cells
-
-
?
3-chlorocatechol + O2
2-chloro-cis,cis-muconate
1.7% activity compared to catechol
-
-
?
3-chlorocatechol + O2
2-chloro-cis,cis-muconate
1.7% activity compared to catechol
-
-
?
3-ethylcatechol + O2
2-ethyl-cis,cis-muconic acid
-
poor substrate
-
?
3-isopropylcatechol + O2
2-isopropyl-cis,cis-muconate
-
-
-
-
?
3-methylcatechol + O2
(2Z,4Z)-2-methylhexa-2,4-dienedioate
-
-
-
-
?
3-methylcatechol + O2
(2Z,4Z)-2-methylhexa-2,4-dienedioate
-
-
-
-
?
3-methylcatechol + O2
(2Z,4Z)-2-methylhexa-2,4-dienedioate
-
-
-
-
?
3-methylcatechol + O2
(2Z,4Z)-2-methylhexa-2,4-dienedioate
the enzyme preferentially recognizes 4-substituted over 3-substituted catechols
-
-
?
3-methylcatechol + O2
(2Z,4Z)-2-methylhexa-2,4-dienedioate
the enzyme preferentially recognizes 4-substituted over 3-substituted catechols
-
-
?
3-methylcatechol + O2
(2Z,4Z)-2-methylhexa-2,4-dienedioate
-
-
-
-
?
3-methylcatechol + O2
(2Z,4Z)-2-methylhexa-2,4-dienedioate
-
-
-
?
3-methylcatechol + O2
(2Z,4Z)-2-methylhexa-2,4-dienedioate
-
poor substrate
-
?
3-methylcatechol + O2
(2Z,4Z)-2-methylhexa-2,4-dienedioate
-
poor substrate
-
?
3-methylcatechol + O2
(2Z,4Z)-2-methylhexa-2,4-dienedioate
-
poor substrate
-
-
?
3-methylcatechol + O2
(2Z,4Z)-2-methylhexa-2,4-dienedioate
-
poor substrate
-
-
?
3-methylcatechol + O2
(2Z,4Z)-2-methylhexa-2,4-dienedioate
-
poor substrate
-
-
?
3-methylcatechol + O2
(2Z,4Z)-2-methylhexa-2,4-dienedioate
-
poor substrate
-
-
?
3-methylcatechol + O2
(2Z,4Z)-2-methylhexa-2,4-dienedioate
-
-
-
?
3-methylcatechol + O2
(2Z,4Z)-2-methylhexa-2,4-dienedioate
-
-
-
-
?
3-methylcatechol + O2
(2Z,4Z)-2-methylhexa-2,4-dienedioate
-
-
-
-
?
3-methylcatechol + O2
(2Z,4Z)-2-methylhexa-2,4-dienedioate
104% activity compared to catechol
-
-
?
3-methylcatechol + O2
(2Z,4Z)-2-methylhexa-2,4-dienedioate
104% activity compared to catechol
-
-
?
3-methylcatechol + O2
(2Z,4Z)-2-methylhexa-2,4-dienedioate
-
-
-
-
?
3-methylcatechol + O2
(2Z,4Z)-2-methylhexa-2,4-dienedioate
117.4% compared to the activity with catechol
-
-
?
3-methylcatechol + O2
(2Z,4Z)-2-methylhexa-2,4-dienedioate
9.9% compared to the activity with catechol
-
-
?
3-methylcatechol + O2
(2Z,4Z)-2-methylhexa-2,4-dienedioate
Sphingobium scionense DSM 19371
9.9% compared to the activity with catechol
-
-
?
3-methylcatechol + O2
(2Z,4Z)-2-methylhexa-2,4-dienedioate
Sphingobium scionense DSM 19371
117.4% compared to the activity with catechol
-
-
?
3-methylcatechol + O2
2-methyl-cis,cis-muconate
-
10% of the activity with catechol
-
-
?
3-methylcatechol + O2
2-methyl-cis,cis-muconate
-
10% of the activity with catechol
-
-
?
3-methylcatechol + O2
2-methyl-cis,cis-muconate
-
64% of activity with catechol
-
-
?
3-methylcatechol + O2
2-methyl-cis,cis-muconate
-
64% of activity with catechol
-
-
?
3-methylcatechol + O2
2-methyl-cis,cis-muconate
-
enzyme from aniline-grown cells: 74% of the activity with catechol, enzyme from L-malate-grown cells: 71% of the activity with catechol
-
-
?
3-methylcatechol + O2
2-methyl-cis,cis-muconate
11.6% of the activity with catechol
-
-
?
3-methylcatechol + O2
2-methyl-cis,cis-muconate
11.6% of the activity with catechol
-
-
?
3-methylpyrocatechol + O2
2,3,5-trimethyl-cis-cis-muconate
-
-
-
-
?
3-methylpyrocatechol + O2
2,3,5-trimethyl-cis-cis-muconate
-
-
-
-
?