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EC 1.3.99.15 Details
EC number
1.3.99.15
Accepted name
benzoyl-CoA reductase
Reaction
benzoyl-CoA + reduced acceptor + 2 ATP + 2 H2O = cyclohexa-1,5-diene-1-carbonyl-CoA + acceptor + 2 ADP + 2 phosphate
Other name(s)
benzoyl-CoA reductase (dearomatizing)
Systematic name
cyclohexa-1,5-diene-1-carbonyl-CoA:acceptor oxidoreductase (aromatizing, ATP-forming)
CAS registry number
176591-18-7
Comment
An iron-sulfur protein. Requires Mg2+ or Mn2+. Reduced methyl viologen can act as electron donor. Inactive towards aromatic acids that are not CoA esters but will also catalyse the reaction: ammonia + acceptor + 2 ADP + 2 phosphate + H2O = hydroxylamine + reduced acceptor + 2 ATP. In the presence of reduced acceptor, but in the absence of oxidizable substrate, the enzyme catalyses the hydrolysis of ATP to ADP plus phosphate.
History
created 1999, deleted 2011
EC Tree
1.3.99.9 created 1976, deleted 2002