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1.1.99.36: alcohol dehydrogenase (nicotinoprotein)

This is an abbreviated version!
For detailed information about alcohol dehydrogenase (nicotinoprotein), go to the full flat file.

Wordmap for 1.1.99.36

Word Map on EC 1.1.99.36 Wordmap for 1.1.99.36

Reaction

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ethanol
+
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acceptor
=
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acetaldehyde
 +
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reduced acceptor

Synonyms

4-nitroso-N, N-dimethylaniline-dependent alcohol dehydrogenase, NDMA-ADH, NDMA-dependent alcohol dehydrogenase, np-ADH

ECTree

     1 Oxidoreductases
         1.1 Acting on the CH-OH group of donors
             1.1.99 With unknown physiological acceptors
                EC 1.1.99.361.1.99.36 alcohol dehydrogenase (nicotinoprotein)

Substrates Products

Substrates Products on EC 1.1.99.36 - alcohol dehydrogenase (nicotinoprotein)

for references in articles please use BRENDA:EC1.1.99.36

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SUBSTRATE
PRODUCT
REACTION DIAGRAM
ORGANISM
UNIPROT
LITERATURE
COMMENTARY hide
Reversibility
r=reversible
ir=irreversible
?=not specified
1-butanol + N,N-dimethyl-4-nitrosoaniline
butanal + 4-(hydroxylamino)-N,N-dimethylaniline
show the reaction diagram
1-butanol + N,N-dimethyl-4-nitrosoaniline
butanaldehyde + 4-(hydroxylamino)-N,N-dimethylaniline
show the reaction diagram
Substrates: -
Products: -
?
1-hexanol + N,N-dimethyl-4-nitrosoaniline
hexanal + 4-(hydroxylamino)-N,N-dimethylaniline
show the reaction diagram
Substrates: -
Products: -
?
1-propanol + N,N-dimethyl-4-nitrosoaniline
propanaldehyde + 4-(hydroxylamino)-N,N-dimethylaniline
show the reaction diagram
Substrates: -
Products: -
?
2-butanol + N,N-dimethyl-4-nitrosoaniline
butanone + 4-(hydroxylamino)-N,N-dimethylaniline
show the reaction diagram
Substrates: -
Products: -
?
2-propanol + N,N-dimethyl-4-nitrosoaniline
acetone + 4-(hydroxylamino)-N,N-dimethylaniline
show the reaction diagram
Substrates: -
Products: -
?
acetate + N,N-dimethyl-4-nitrosoaniline
? + 4-(hydroxylamino)-N,N-dimethylaniline
show the reaction diagram
Substrates: -
Products: -
?
acetophenone + 1-propanol
?
show the reaction diagram
-
Substrates: 4.3% yield, enantiomeric excess of 0.99 for (S)-product chiral secondary alcohol
Products: 3.8% yield, enantiomeric excess of 0.99 for (S)-product
r
acetophenone + cyclohexanol
?
show the reaction diagram
-
Substrates: 2.8-3.7% yield, depending on the ratio of substrates, enantiomeric excess of 0.95-0.99 for (S)-product chiral secondary alcohol
Products: 3.8% yield, enantiomeric excess of 0.99 for (S)-product
r
acetophenone + ethanol
?
show the reaction diagram
-
Substrates: 3.8% yield, enantiomeric excess of 0.99 for (S)-product chiral secondary alcohol
Products: 3.8% yield, enantiomeric excess of 0.99 for (S)-product
r
ethanol + N,N-dimethyl-4-nitrosoaniline
acetaldehyde + 4-(hydroxylamino)-N,N-dimethylaniline
show the reaction diagram
methanol + N,N-dimethyl-4-nitrosoaniline
formaldehyde + 4-(hydroxylamino)-N,N-dimethylaniline
show the reaction diagram
additional information
?
-