1.1.1.309: phosphonoacetaldehyde reductase (NADH)
This is an abbreviated version!
For detailed information about phosphonoacetaldehyde reductase (NADH), go to the full flat file.
Reaction
Synonyms
PhpC
ECTree
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Substrates Products
Substrates Products on EC 1.1.1.309 - phosphonoacetaldehyde reductase (NADH)
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REACTION DIAGRAM
2-hydroxyethylphosphonate + NAD+
phosphonoacetaldehyde + NADH + H+
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the catalytic efficiency of phosphonoacetaldehyde reduction is 377fold greater than that of the reverse reaction, and even at pH 9.0, the catalytic efficiency of the forward reaction is still 11fold greater than that of the reverse reaction
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r
phosphonoacetaldehyde + NADPH + H+
2-hydroxyethylphosphonate + NADP+
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the reaction proceeds to apparent completion in the presence of NADH, but to a lesser extent with NADPH, which suggests that NADH is the preferred cofactor
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additional information
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no reaction is observed with hydroxymethylphosphonate and 3-hydroxypropylphosphonate
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?
2-hydroxyethylphosphonate + NAD+
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the enzyme catalyzes a step in the phosphinothricin tripeptide pathway
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phosphonoacetaldehyde + NADH + H+
2-hydroxyethylphosphonate + NAD+
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the reaction proceeds to apparent completion in the presence of NADH, but to a lesser extent with NADPH, which suggests that NADH is the preferred cofactor
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-
?