EC Number |
Substrates |
Organism |
Products |
Reversibility |
---|
2.5.1.80 | 2-pentenyl diphosphate + L-tryptophan |
C-5 prenylation |
Aspergillus fumigatus |
diphosphate + 5-(pent-2-enyl)-L-tryptophan |
- |
? |
2.5.1.80 | benzyl diphosphate + L-tryptophan |
C-5 prenylation |
Aspergillus fumigatus |
diphosphate + 5-benzyl-L-tryptophan |
- |
? |
2.5.1.80 | dimethylallyl diphosphate + 1,6-dihydroxynaphthalene |
- |
Aspergillus fumigatus |
diphosphate + 4-(3-methylbut-2-en-1-yl)naphthalene-1,6-diol |
- |
? |
2.5.1.80 | dimethylallyl diphosphate + 1,7-dihydroxynaphthalene |
- |
Aspergillus fumigatus |
diphosphate + 4-(3-methylbut-2-en-1-yl)naphthalene-1,7-diol |
- |
? |
2.5.1.80 | dimethylallyl diphosphate + 1-methyl-DL-tryptophan |
- |
Aspergillus fumigatus |
diphosphate + 1-methyl-4-(3-methylbut-2-enyl)-DL-tryptophan |
- |
? |
2.5.1.80 | dimethylallyl diphosphate + 1-methyl-L-tryptophan |
- |
Aspergillus fumigatus |
diphosphate + 1-methyl-7-(3-methylbut-2-enyl)-L-tryptophan |
35.8% of the yield with L-tryptophan |
? |
2.5.1.80 | dimethylallyl diphosphate + 1-naphthol |
- |
Aspergillus fumigatus |
diphosphate + 4-(3-methylbut-2-en-1-yl)naphthalen-1-ol |
- |
? |
2.5.1.80 | dimethylallyl diphosphate + 11-methyl-DL-tryptophan |
- |
Aspergillus fumigatus |
diphosphate + 11-methyl-DL-7-(gamma,gamma-dimethylallyl)tryptophan |
19.1% of the yield with L-tryptophan |
? |
2.5.1.80 | dimethylallyl diphosphate + 11-methyl-DL-tryptophan |
tandem incubation of dimethylallyltryptophan synthases FgaPT2 and 7-DMATS (EC 2.5.1.34 and EC 2.5.1.80) leads to the production of diprenylated indole derivatives. Yield of diprenylated product: 33.5% (FgaPT2 followed by 7-DMATS), 4.8% (7-DMATS followed by FgaPT2) |
Aspergillus fumigatus |
? |
- |
? |
2.5.1.80 | dimethylallyl diphosphate + 11-methyl-DL-tryptophan |
- |
Aspergillus fumigatus |
diphosphate + 11-methyl-4-(3-methylbut-2-enyl)-DL-tryptophan |
- |
? |