Literature summary for 1.13.11.20 extracted from

Fischer, A.A.; Lindeman, S.V.; Fiedler, A.T.
A synthetic model of the nonheme iron-superoxo intermediate of cysteine dioxygenase (2018), Chem. Commun. (Camb.), 54, 11344-11347 .

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Organism

Organism	UniProt	Comment	Textmining
synthetic construct	-	-	-

General Information

General Information	Comment	Organism
metabolism	nonheme FE(II) complex [Fe(TpMe2)(2-ATP)] , where 2-ATP is 2-aminothiophenolate, models substrate-bound cysteine dioxygenase. The complex reacts with O2 at -80°C to yield a purple intermediat that features a thiolate-ligated Fe(III) center bound to a superoxide radical, mimicking the putative structure of a key CDO intermediate	synthetic construct

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Release 2023.1 (January 2023)