1.1.1.386: ipsdienol dehydrogenase
This is an abbreviated version!
For detailed information about ipsdienol dehydrogenase, go to the full flat file.
Word Map on EC 1.1.1.386
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1.1.1.386
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dntp
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triphosphohydrolase
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samhd1
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triphosphate
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pheromone
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phosphomimetic
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domain-containing
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racemic
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retroviral
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deoxynucleoside
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beetles
- 1.1.1.386
- dntp
-
triphosphohydrolase
- samhd1
- triphosphate
-
pheromone
-
phosphomimetic
-
domain-containing
-
racemic
-
retroviral
- deoxynucleoside
- beetles
Reaction
Synonyms
IDOLDH
ECTree
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Substrates Products
Substrates Products on EC 1.1.1.386 - ipsdienol dehydrogenase
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REACTION DIAGRAM
(4R)-ipsdienol + NAD(P)+
ipsdienone + NAD(P)H + H+
the enzyme is involved in pheromon production
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(4R)-ipsdienol + NAD+
ipsdienone + NADH + H+
no activity with (4S)-ipsdienol. The enzyme shows similar specific activities with NAD+ and NADP+
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(4R)-ipsdienol + NADP+
ipsdienone + NADPH + H+
no activity with (4S)-ipsdienol. The enzyme shows similar specific activities with NAD+ and NADP+
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(R)-ipsdienol + NADP+
ipsdienone + NADPH + H+
stereospecific reaction, no activity with (S)-ipsdienol. The oxidation of (R)-ipsdienol is 6.3times higher than that for the reduction of ipsdienone
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r
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the enzyme stereospecifically reduces both ketones to their corresponding (R)-alcohols. Low activity with (R)-menthone, 3-penten-2-ol, 17beta-estradiol, poor or no activity with (S)-ipsdienol, nerol, geraniol, myrcene, citral, 4-methyl-3-penten-2-one, 4-methyl-2-pentanone, 4-methyl-2-pentanol, acetone, 1,3-butendiol, etanol, 2-propanol, 3-hydroxybutyrate, and 2-oxobutyrate, substrate specificity, overview. Product identification by GC-MS analysis
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additional information
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the enzyme stereospecifically reduces both ketones to their corresponding (R)-alcohols. Low activity with (R)-menthone, 3-penten-2-ol, 17beta-estradiol, poor or no activity with (S)-ipsdienol, nerol, geraniol, myrcene, citral, 4-methyl-3-penten-2-one, 4-methyl-2-pentanone, 4-methyl-2-pentanol, acetone, 1,3-butendiol, etanol, 2-propanol, 3-hydroxybutyrate, and 2-oxobutyrate, substrate specificity, overview. Product identification by GC-MS analysis
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