1.1.1.318: eugenol synthase

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For detailed information about eugenol synthase, go to the full flat file.

Reaction

Synonyms

CbEGS1, CbEGS2, chavicol/eugenol synthase, DcE(I)GS1, DcEGS1, EGS, EGS1, EGS2, eugenol synthase 1, eugenol synthase 2, eugenol synthase 3, eugenol synthase 4, eugenol synthase 5, eugenol synthase 6, eugenol synthase 7, eugenol synthase 8, eugenol/isoeugenol synthase, IEGS1, IEGS2, LtCES1, More, ObEGS1, ObEGS2, ObEGS3, ObEGS4, ObEGS5, ObEGS6, ObEGS7, ObEGS8, PhEGS1, RcEGS1, RhEGS1

ECTree

     1 Oxidoreductases

         1.1 Acting on the CH-OH group of donors

             1.1.1 With NAD⁺ or NADP⁺ as acceptor

                1.1.1.318 eugenol synthase

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Results	in table
35	AA Sequence
19	Cloned(Commentary)
21	Cofactor
5	Crystallization (Commentary)
4	Expression
19	General Information
1	Inhibitors
12	kcat/KM [mM/s]
12	KM Value [mM]
2	Localization
4	Molecular Weight [Da]
19	Natural Substrates/ Products (Substrates)
32	Organism
5	Pathway
7	pH Optimum
1	pH Range
2	pI Value
1	Posttranslational Modification
5	Protein Variants
5	Purification (Commentary)
4	Reaction
25	Reference
52	Source Tissue
1	Specific Activity [micromol/min/mg]
47	Substrates and Products (Substrate)
6	Subunits
53	Synonyms
1	Systematic Name
7	Temperature Optimum [°C]
12	Turnover Number [1/s]

Reaction

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Reaction on EC 1.1.1.318 - eugenol synthase

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REACTION

REACTION DIAGRAM

COMMENTARY

ORGANISM

UNIPROT

LITERATURE

eugenol + a carboxylate + NADP+ = a coniferyl ester + NADPH + H+

4 entries

eugenol + a carboxylate + NADP+ = a coniferyl ester + NADPH + H+

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eugenol + a carboxylate + NADP+ = a coniferyl ester + NADPH + H+

reaction mechanism, overview

Ocimum basilicum

Q15GI4

718314

eugenol + a carboxylate + NADP+ = a coniferyl ester + NADPH + H+

reaction mechanism, detailed overview

Larrea tridentata

-

717154

eugenol + a carboxylate + NADP+ = a coniferyl ester + NADPH + H+

eugenol synthase catalyzes the reductive displacement of acetate from the propenyl side chain of the substrate coniferyl acetate to produce the allyl-phenylpropene eugenol, two-step reaction mechanism involving the formation of a quinone-methide prior to reduction, overview. The formation of this intermediate is promoted by a hydrogen-bonding network that favors deprotonation of the substrate's 4-hydroxyl group and disfavors binding of the acetate moiety, akin to a push-pull catalytic mechanism, involvement of a quinone-methide, a conjugated enone, intermediate in the bond cleavage

Ocimum basilicum

Q15GI4

718254